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21 Nanomaterials and Biopolymers for the Remediation of Polluted Sites
that has been altered by the loosening of the earth, humus formation, chemi-
cal decomposition, and by the transportation of humidification and chemical
decomposition products” [3]. The modern agricultural practices are heavily depen-
dent on the application of chemical pesticides, inorganic fertilizers, and growth
regulators which has not only raised the agriculture production but has also
resulted in depletion of natural resource, environmental deterioration, and loss of
crop diversity [4]. Owing to their exceptional ability to efficiently adsorb as well
as high surface area, biopolymeric nanocomposites are considered as an excellent
support materials of metallic photocatalysis for the removal of contaminants from
the polluted sites. The present chapter envisages about application of various
nanomaterials such as metal/metal oxides and biopolymeric nanocomposites for
effective remediation of water and soil.
21.2
Water Remediation
21.2.1
Application of Nanotechnology for Water Disinfection
and Textile Dye Degradation
The availability of potable water is a serious problem in rural areas of developing
countries. The economic, social, and environmental impacts of poor water supply
and sanitation have posed a lot of implications on the health and safety of the peo-
ple, especially children, elderly, and poor closely associated with the accessibility of
adequate, safe, and affordable water supplies. Hence, there is an increasing demand
for providing potable water to people in both the developed and developing coun-
tries which can be addressed by the development of innovative new technologies
and materials [5].
The textile industry represents a major threat to the environment due to release of
dye effluents into the surrounding water bodies due to consumption of large quan-
tities of water at their different steps of dyeing and finishing process. Due to the
presence of —N=N— bond, synthetic textile dyes often become recalcitrant and
carcinogenic in nature. These synthetic dyes also consists of complex aromatic struc-
tures which cannot be easily degraded. Most of the synthetic dyes have been inten-
tionally designed to resist aerobic microbial degradation and are converted to toxic
or carcinogenic compounds [6].
The traditional techniques deployed for the removal of dyestuff are the application
of biological, adsorption, and coagulation. Each of the method has its own advan-
tages as well as bottlenecks.
In recent years, emergence of nanotechnology has been the subject of extensive
research and can provide us ways to purify air, water, and soil using engineered
nanoparticles as catalysts. Nanotechnology is defined as the “deliberate manipula-
tion of matter at a scale of 1–100 nm.” This process involving deliberate manipu-
lation of matter size scales of less than 100 nm offers the possibility of an efficient
removal of pollutants, mutagens, and microorganisms pertaining to the area of water
purification, air purification, and soil remediation. Furthermore, the utilization of